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The
principles of titanium oxide photocatalysts and photocatalytic
reactions have been briefly introduced as compared to the
photosynthesis in green plants. Photocatalysis can be considered the
most important and new, environmentally friendly, clean chemical
technology for green chemistry. In fact, various applications of
titanium oxide photocatalysts have already been developed to better
our environment. Especially, these include successful developments
in the purification of the polluted atmosphere. The design and
development of such unique titanium oxide photocatalysts can be
considered a breakthrough in the efficient and large-scale
utilization of solar energy.
The photocatalytic reactivity of
titanium oxides can be applied for the reduction or elimination of
polluted compounds in air such as NOx, cigarette smoke, as well as
volatile compounds arising from various construction materials.
Also, high photocatalytic reactivity can be applied to protect
lamp-houses and walls in tunneling, as well as to prevent white
tents from becoming sooty and dark. Atmospheric
constituents such as chlorofluorocarbons (CFCs) and CFC substitutes,
greenhouse gases, and nitrogenous and sulfurous compounds undergo
photochemical reactions either directly or indirectly in the
presence of sunlight. In a polluted area, these pollutants can
eventually be removed.
Titanium oxide thin films have been
found to exhibit a unique and useful function (i.e., a
super-hydrophilic property). Usually, metal oxide surfaces such as
titanium oxides become cloudy when water is dropped on them because
the contact angle of the water droplet and the surface is 50–80
degrees.
The use of UV light bulbs to
photocatalytically destroy pollutants provides extremely simple
controls. The unit can be turned on or off with the flip of a light
switch. The ambient operating temperature result in low energy
consumption, and provides low cost.
The
process can be integrated with other flue gas cleanup technologies
to achieve ultra-low Nox and SO2 emissions. In addition, it offers
the following distinctive advantages:
- Potential
utilization of solar energy with semiconductor particles (TiO2)
- No
extra reactants such as NH3 or O3 required
- Low
temperature operations
- Nox
recovered as nitric acid, a potential raw material for
fertilizers
Some
practical applications are as follows:
-
Air
cleaner containing TiO2 photocatalysts.
-
Systems
for the purification of polluted air, e.g., the elimination of
NOx
-
Super-hydrophilic,
self-cleaning systems, and coating materials for cars.
-
Soundproof
walls using TiO2 photocatalysts
-
Photocatalyst
coated lamps (or lamp covers
-
Cement
containing TiO2 photocatalysts
-
Coating
materials for architectural walls.
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